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Find a shop with an experienced technician that can do a back pressure test on the exhaust system. Theres 3 cats on that car. If you have one of them starting to clog up or something you can have a situation where without the a/c, the cooling system can handle the extra heat buildup, but once the a/c is on, it cant keep up with the extra heat from the condenser.
In some extreme cases, a completely clogged cat will not allow the vehicle to start and run. In slightly less extreme, you can get overheating issues, or even misfires. Usually accompanied with a lack of power on acceleration. In this case you may not have reached that point, and you have a partially clogged cat where its only slightly more difficult for the engine to breath out but enough to exceed the limit of the coolant system with extra load.
Also, is it just one car doing this now? or are both cars still having this same issue?
In some extreme cases, a completely clogged cat will not allow the vehicle to start and run. In slightly less extreme, you can get overheating issues, or even misfires. Usually accompanied with a lack of power on acceleration. In this case you may not have reached that point, and you have a partially clogged cat where its only slightly more difficult for the engine to breath out but enough to exceed the limit of the coolant system with extra load.
Also, is it just one car doing this now? or are both cars still having this same issue?