To answer this correctly.
Compression Ratio (also known as CR) is the difference in volume inside the cylinder with the piston at bottom of the stroke to the top of the stroke. A 10:1 CR means the volume at piston BDC (bottom dead center) is 10 times as much as when at TDC (top dead center).
Compression pressure (typically when checking the condition of the cylinder, valves and rings while cranking the engine) is a function of condition of parts, altitude (high altitude is lower pressure due to less air) and crank speed. Typically you should se a value a bit more than.....Ambient air pressure (get from a weather site) times CR.
Example, with everything good at sealevel (14PSI), a 10:1 CR should be over 150PSI due to dynamic filling of cylinder while cranking. Basic goal is having all pressures within 10% from lowest to highest.